Supramolecular Catalysts Are The Catalysts That Are Functioned On A Molecular Level, Understanding Of Which Is Critical In The Advancement Of Green Chemistry. These Catalysts Are Synthesized By Using Smaller Molecules And Compounds Of Different Properties That Are Linked Together With Non-Covalent Interactions Like Hydrogen Bonding, Photo- And Electro-Chemical As Well As Host-Guest Interactions. As These Supramolecular Catalysts Are Made Up Of Low-Cost Materials And Available In Various Shapes And Sizes, They Are Highly Preferred For Catalysis So As To Reduce The Complexity Of The Reaction Process. Supramolecular Catalysts Offer Exciting Advantages Over The Traditional Homogenous Catalysts. These Catalysts Are More Cost-Effective, Allowing For A Lower Production Cost, And Also Can Be Easily Recycled As The Individual Components Can Be Separated More Easily. Moreover, These Catalysts Can Be Effectively Used For Multiple Functionalities Due To Their Degradable Nature. An Interesting Use Of This Type Of Catalyst Is Their Role In The Bio-Catalysis Of Enzymatic Reactions. Here, The Supramolecular Catalyst Acts As A Stabilizing Factor By Moderating The Overall Activity Of The Enzyme, Thus Increasing The Rate Of The Enzymatic Reaction. Due To Their Broad Range Of Advantages, Supramolecular Catalysts Could Be Combined With Various Organic And Inorganic Materials, To Make Them Suitable For Specific Applications. For Example, Their Hydrophilic Character Can Be Increased By Complexing Them With Hydrophilic Polymers, Thus Making Them More Efficient For A Wide Range Of Water-Based Reactions. Similarly, The Phase Transfer Platform That Allows Using A Cationic-Biphasic Catalyst In A Heterogeneous Reaction System Has Been Used In Organic Syntheses. In Conclusion, Supramolecular Catalysts Have Gained Wider Application Prospects In Various Fields Of Science And Technology.
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Stanislaw Dzwigaj, Sorbonne Université, France
Title : Distal functionalization via transition metal catalysis
Haibo Ge, Texas Tech University, United States